2H-Azepine, 3,4,5,6-tetrahydro-7-methoxy- → 2,4-Diamino-6-(5-aminopentyl)-1,3,5-triazine

HRID 34783

Reaktionsgleichung

Reaktionsgleichung von HRID 34783
[NH2:1][C:2]([NH:4][C:5]([NH2:7])=[NH:6])=[NH:3].CO[C:10]1[CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][N:11]=1>C(O)C>[NH2:6][C:5]1[N:4]=[C:2]([NH2:1])[N:3]=[C:12]([CH2:13][CH2:14][CH2:15][CH2:16][CH2:10][NH2:11])[N:7]=1

Komponenten

4

Edukt 2

HCID 756572H-Azepine, 3,4,5,6-tetrahydro-7-methoxy-HCID 176517607Carbamimidamidomethanimidamide

Produkt 1

HCID 212987902,4-Diamino-6-(5-aminopentyl)-1,3,5-triazine

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

A mixture of biguanide (1.05 g.), 4,5,6,7-tetrahydro-2-methoxy-3H-azepine (1.27 g.) and ethanol (50 ml.) was heated under reflux for 18 hours, cooled and the solid that crystallised was collected to give 2,4-diamino-6-(5-aminopentyl)-1,3,5-triazine which was used without further purification.

Aufarbeitung

  1. temperaturewas heated
  2. temperatureunder reflux for 18 hours
  3. temperaturecooled
  4. customthe solid that crystallised
  5. customwas collected

Quellen und Nachweise

ORD-Eintrag
ord-d160538931fd480d9675ac1086279244
Quelldatensatz
uspto-grants-1988_08
Patentnummer
US04762932

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