Benzenamine, 2-phenoxy- → 1-Isothiocyanato-2-phenoxybenzene
Reaktionsgleichung
[C:1](C1NC=CN=1)(C1NC=CN=1)=[S:2].[O:13]([C:20]1[CH:26]=[CH:25][CH:24]=[CH:23][C:21]=1[NH2:22])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>C1COCC1>[O:13]([C:20]1[CH:26]=[CH:25][CH:24]=[CH:23][C:21]=1[N:22]=[C:1]=[S:2])[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
1.96 g (0.011 mol) of thiocarbonyl diimidazole were added to a solution of 1.85 g (0.01 mol) of 2-phenoxyaniline in 50 ml of THF and the mixture was stirred at room temperature for 4 hours, giving, after removal of the solvent by distillation, the compound as a brown amorphous product.
Aufarbeitung
- customgiving
- customafter removal of the solvent
- distillationby distillation
Quellen und Nachweise
- ORD-Eintrag
- ord-853bee71781a42c6a85dc3d3c78adb8d
- Quelldatensatz
- uspto-grants-2007_02
- Patentnummer
- US07179829B2
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