Reaktionsgleichung
[C:1]([CH2:4][NH:5][CH:6]([CH2:9][CH2:10][CH2:11][CH:12]=[CH2:13])C=C)([OH:3])=[O:2].[Cl-].C([N+]1C=CC=CC=1)CCC.[Cl-].[Cl-].[Cl-].[Al+3]>C1CCC([P+](C([P+](C2CCCCC2)(C2CCCCC2)C2CCCCC2)C2C=CC=CC=2)(C2CCCCC2)C2CCCCC2)CC1.Cl[Ru]Cl>[C:1]([CH2:4][NH:5][C:6]1[CH2:9][CH2:10][CH2:11][CH2:12][CH:13]=1)([OH:3])=[O:2]Komponenten
5
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
92 mg (0.5 mmol) of N-carboxymethyl-3-amino-1,7-octadiene and 4 mg of bis(tricyclohexylphosphine)benzylideneruthenium(IV) dichloride (1 mol %) were dissolved in a liquid mixture of 684 mg of N-butylpyridinium chloride (4 mmol) and 533 mg of aluminium trichloride (4 mmol) under an argon atmosphere in a baked-out Schlenk tube. The mixture was allowed to react for two hours at 50° C. After an aqueous work-up, the mixture was filtered through a very short silica gel column (0.5 cm), washed four times with 1 ml each time of acetonitrile and evaporated.
Aufarbeitung
- customto react for two hours at 50° C
- filtrationAfter an aqueous work-up, the mixture was filtered through a very short silica gel column (0.5 cm)
- washwashed four times with 1 ml each time of acetonitrile
- customevaporated
Quellen und Nachweise
- ORD-Eintrag
- ord-61797f3085e84e62a257231010c0c0fe
- Quelldatensatz
- uspto-grants-2004_06
- Patentnummer
- US06756500B1
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