Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Phloroglucinol | HCID 359 | — |
| Edukt | 2,4-Dihydroxybenzoic Acid | HCID 1491 | — |
| Edukt | 1,1,1-Tris(4-hydroxyphenyl)ethane | HCID 93118 | — |
| Edukt | 1,3,5-Tris(4-hydroxyphenyl)benzene | HCID 348148 | — |
| Edukt | Tri-(4-hydroxyphenyl)-phenyl methane | HCID 17820215 | — |
| Edukt | 2-(4-Hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propane | HCID 21885520 | — |
| Edukt | 4,6-Dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane | HCID 21894433 | — |
| Produkt | Bisphenol P | HCID 630355 | — |
Reaktionsschritte
The polycarbonates may, of course, be branched by incorporating small quantities of polyhydroxyl compounds, e.g. 0.05 to 2.0 mols percent (based on the quantity of bisphenols). Polycarbonates of this kind have been described, e.g. in German Offenlegungsschriften No. 1,570,533; 2,116,974 and 2,113,347, in British Patents No. 885,442 and 1,079,821 and in U.S. Pat. No. 3,544,514. The following are some of the polyhydroxyl compounds which are suitable for this purpose: Phloroglucinol, 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptene-(2), 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane, 1,3,5-tri-(4-hydroxyphenyl)-benzene, 1,1,1-tri-(4-hydroxyphenyl)-ethane, tri-(4-hydroxyphenyl)-phenyl-methane, 2,2-bis-[4,4-(4,4'-dihydroxydiphenyl)-cyclohexyl]-propane, 2,4-bis-(4-hydroxyphenyl-4-isopropyl)-phenol,2,6-bis-(2'-hydroxy-5'-methyl-benzyl)-4-methylphenol, 2,4-dihydroxybenzoic acid, 2-(4-hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propane and 1,4-bis-(4',40"-dihydroxytriphenyl-methyl)-benzene.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | USRE031165 |
|---|
| Quelldatensatz | uspto-grants-1983_03 |
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| ORD ID | ord-6ada6bb5c4e344879e79e1c331e424be |
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| Quellennotiz | uspto-grants-1983_03 |
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