Tributylvinyltin → HCID 18940943, Verbindung

HRID 356038Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 356038
[C:1]([N:4]1[C:12]2[C:7](=[CH:8][C:9](I)=[C:10]([Cl:13])[CH:11]=2)[CH2:6][CH2:5]1)(=[O:3])[CH3:2].[CH:15]([Sn](CCCC)(CCCC)CCCC)=[CH2:16]>>[C:1]([N:4]1[C:12]2[C:7](=[CH:8][C:9]([CH:15]=[CH2:16])=[C:10]([Cl:13])[CH:11]=2)[CH2:6][CH2:5]1)(=[O:3])[CH3:2]

Komponenten

3

Edukt 2

HCID 81998TributylvinyltinHCID 18940886HCID 18940886, Verbindung

Produkt 1

HCID 18940943HCID 18940943, Verbindung

Versuchsvorschrift

1-Acetyl-6-chloro-5-iodoindoline (D60) (0.19 g, 0.6 mmol) was treated with vinyl tributyltin as in the method developed by Stille (A. M. Echavarren and J. K. Stille, J. Am. Chem. Soc., 1987, 109, 5478) to give the title compound (0.13 g) as a brown oil which was used without further purification.

Quellen und Nachweise

ORD-Eintrag
ord-5244586881274912802ac99e6c10b71e
Quelldatensatz
uspto-grants-1998_11
Patentnummer
US05834494

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