Acetyl chloride → HCID 137226513, Verbindung

HRID 35962

Reaktionsgleichung

Reaktionsgleichung von HRID 35962
[Cl:1][C:2](=[N:7][OH:8])[C:3]([Cl:6])=[N:4][OH:5].[C:9](Cl)(=[O:11])[CH3:10].C(N(CC)CC)C>ClC(Cl)C>[C:9]([OH:11])(=[O:5])[CH3:10].[C:9]([OH:11])(=[O:5])[CH3:10].[Cl:1][C:2](=[N:7][OH:8])[C:3]([Cl:6])=[N:4][OH:5]

Komponenten

5

Edukt 3

HCID 6367Acetyl chlorideHCID 8471TriethylamineHCID 135527345Ethanediimidoyl dichloride, dihydroxy-

Produkt 1

HCID 137226513HCID 137226513, VerbindungAusbeute 30 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 63651,1-DichloroethaneLösungsmittel

Versuchsvorschrift

The mixture of 2.0 g (0.0127 mol) of dichloroglyoxime (Compound No.6), 20 ml of dichloroethane and 2.4 g (0.0306 mol) of acetyl chloride was stirred in an ice bath. To the mixture, triethylamine (3.1 g, 0.0307 mol) was added dropwise, followed by stirring for 30 minutes. The reaction mixture was washed twice with 15 ml of water. The dichloroethane solution was concentrated under reduced pressure, to obtain white crystals of dichloroglyoxime diacetate (Compound No.2, yield: 30%).

Aufarbeitung

  1. stirringby stirring for 30 minutes
  2. washThe reaction mixture was washed twice with 15 ml of water
  3. concentrationThe dichloroethane solution was concentrated under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-8cf7e900532942bd97b5cb69fa438ac1
Quelldatensatz
uspto-grants-1995_05
Patentnummer
US05411990

Verknüpfte Notizen

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