1,2-Diallyloxybenzene → 1,2-Diallyloxybenzene

HRID 361131Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 361131
C=CCOc1ccccc1OCC=C>CCOC(C)=O.O=C1CC[C@H]2CO[C@@H]1O2>C=CCc1ccc(CC=C)c(O)c1O.C=CCc1ccc(O)c(O)c1CC=C

Komponenten

7

Edukt 1

HCID 778941,2-Diallyloxybenzene

Produkt 3

HCID 778941,2-DiallyloxybenzeneAusbeute 53,895 %HCID 131583253,4-Diallylbenzene-1,2-diolAusbeute 16,1 %HCID 132276783,6-Bis(prop-2-enyl)benzene-1,2-diolAusbeute 19,451 %

Reagenzien, Katalysatoren, Lösungsmittel 3

HCID 8857Ethyl AcetateLösungsmittelHCID 10975499(1S,5R)-6,8-Dioxabicyclo[3.2.1]octan-4-oneLösungsmittelHCID 7500EthylbenzeneInterner Standard

Reaktionsbedingungen

Temperatur
200 °C
Sonstiges
Reaction carried out in transient flow with ramps to vary the binary solvent composition, temperature and residence time. This reaction represents a single HPLC measurement sampled from within a transient flow ramp. Conditions are an estimate of what the reaction sample was exposed to prior to analysis.

Aufarbeitung

  1. temperatureThe solution flowed through a customized cooling system made from an aluminum block and a Peltier assembly to quench the reaction.
  2. aliquotA Vici 4 port 2 position sampling valve sampled small aliquots (500 nL) into the HPLC for online analysis measurements of the reaction.

Quellen und Nachweise

ORD-Eintrag
ord-598dd6379fe142b3913255f4998b6803
Quelldatensatz
Transient flow exploration of the effect of temperature, residence time and binary solvent ratios on a uni-molecular allyl substituted catechol reaction.
Originallink
Quelle ansehen

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