Chlorotrimethylsilane → Silane, trimethyl[[2-methyl-1-(1-methylethyl)-1-propenyl]oxy]-

HRID 363728

Reaktionsgleichung

Reaktionsgleichung von HRID 363728
[CH3:1][CH:2]([C:4](=[O:8])[CH:5]([CH3:7])[CH3:6])[CH3:3].[CH3:9][Si:10](Cl)([CH3:12])[CH3:11]>>[CH3:1][C:2](=[C:4]([O:8][Si:10]([CH3:12])([CH3:11])[CH3:9])[CH:5]([CH3:7])[CH3:6])[CH3:3]

Komponenten

3

Edukt 2

HCID 6397ChlorotrimethylsilaneHCID 112712,4-Dimethyl-3-pentanone

Produkt 1

HCID 11095327Silane, trimethyl[[2-methyl-1-(1-methylethyl)-1-propenyl]oxy]-

Versuchsvorschrift

Reaction between 2,4-dimethyl-3-pentanone (1.2.4.3), trimethylsilyl chloride, and base gave 2,4-dimethyl-3-trimethysilyloxy-2-pentene (1.2.4.4) which was reacted with 1-fluoropyridinium triflate (1.2.4.5) to form 2,4-dimethyl-2-fluoro-3-pentanone (1.2.4.6). This product was reacted with (CH3)3S(O)+I- to form the title compound (1.2.4.2). ##STR31##

Quellen und Nachweise

ORD-Eintrag
ord-12c500d629034589a9aeeb6f309ba54c
Quelldatensatz
uspto-grants-1999_02
Patentnummer
US05874573

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