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Glycerol → Ethylene Oxide

HRID 369560
Notizen
Druckvorschau

Reaktionsgleichung

Reaktionsgleichung von HRID 369560
[C:1]([O-:5])(=[O:4])[CH:2]=C.[C:6]([O-:11])(=O)[C:7]([CH3:9])=[CH2:8].[OH:12][CH2:13][CH:14]([CH2:16][OH:17])O>>[CH2:1]1[O:5][CH2:2]1.[CH2:6]1[O:11][CH:7]1[CH3:8].[CH2:1]([C:14]([CH2:13][OH:12])([CH2:16][OH:17])[CH2:6][CH3:7])[OH:4].[CH2:1]([C:7]([CH2:6][OH:11])([CH2:8][OH:12])[CH3:9])[OH:4]
KomponentenVersuchsvorschriftAufarbeitungQuellen und NachweiseNotizen zur Reaktion

Komponenten

7

Edukt 3

HCID 753GlycerolHCID 25188AcrylateHCID 87595Methacrylate

Produkt 4

HCID 6354Ethylene OxideHCID 6378Propylene OxideHCID 6502TrimethylolethaneHCID 6510Trimethylolpropane

Versuchsvorschrift

As a compound having at least one addition polymerizable ethylenically unsaturated group and a boiling point of 100° C. or more under normal pressure, there can be exemplified a monofunctional acrylate and methacrylate such as polyethylene glycol mono(meth)acrylate, polypropylene glycol mono(meth)acrylate, and phenoxyethyl(meth)acrylate; compounds obtained by the addition of ethylene oxide or propylene oxide to polyfunctional alcohol such as polyethylene glycol di(meth)acrylate, trimethylolethane tri(meth)acrylate, neopentyl glycol di(meth)acrylate, pentaerythritol tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, dipentaerythritol hexa(meth)acrylate, hexanediol (meth)acrylate, trimethylolpropane, tri(acryloyloxypropyl) ether, tri(acryloyloxyethyl)isocyanurate, glycerin, and trimethylolethane, and then having (meth)acrylated; urethane acrylates as disclosed in JP-B-48-41708, JP-B-50-6034, and JP-A-51-37193; polyester acrylates as disclosed in JP-A-48-64183, JP-B-49-43191, and JP-B-52-30490; and polyfunctional acrylates and methacrylates such as epoxy acrylates which are reaction products of epoxy resins and (meth)acrylic acids. Further, photocurable monomers and oligomers described in Nihon Setchaku Kyokai Shi (Bulletin of Japan Adhesion Association), Vol. 20, No. 7, pp. 300 to 308 can also be used.

Aufarbeitung

  1. additionAs a compound having at least one addition polymerizable ethylenically unsaturated group

Quellen und Nachweise

ORD-Eintrag
ord-a78982045c854d8cbac73881e89e8b05
Quelldatensatz
uspto-grants-2000_10
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US06140016

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