HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
6-Methoxyquinoline → Quinoline, 1,2,3,4-tetrahydro-6-methoxy-
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 6-Methoxyquinoline | HCID 14860 | — |
| Katalysator | Palladium | HCID 23938 | — |
| Lösungsmittel | Ethanol | HCID 702 | — |
| Produkt | Quinoline, 1,2,3,4-tetrahydro-6-methoxy- | HCID 67113 | 94,6% |
Reaktionsschritte
6-Methoxyquinoline (1.00g) was dissolved in absolute ethanol (20 ml) and hydrogenated under pressure in the presence of 10% palladium on charcoal (0.10g) with shaking for about 40 hours. Filtration and evaporation to dryness of the filtrate gave 1,2,3,4-tetrahydro-6-methoxyquinoline as a light-brown gum (0.97g). The structure was supported by nmr spectrum.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04087561 |
| Quelldatensatz | uspto-grants-1978_05 |
| ORD ID | ord-1d27416b936e4f4b9c7fc294a512a2d7 |
| Quellennotiz | uspto-grants-1978_05 |