Oxygen → Bicyclo(2.2.1)heptan-2-one
Reaktionsgleichung
[CH:1]12[CH2:7][CH:4]([CH2:5][CH2:6]1)[CH:3]=[CH:2]2.[O:8]=O>>[CH:1]12[CH2:7][CH:4]([CH2:5][CH2:6]1)[CH2:3][C:2]2=[O:8].[C:1]1([CH:7]=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=1Komponenten
4
Versuchsvorschrift
7.1 g norbornene and 1 atm O2 were passed over 100 mg of this material at 280° C. for 2 hours, yielding in a partial conversion 99 mg norbornanone (relative yield 70%) and 43 mg cyclohexene carboxaldehyde (relative yield 30%) with a turnover frequency of 160 moles total product per mole Rh per hr.
Quellen und Nachweise
- ORD-Eintrag
- ord-4bb6ecef8ce947c0a9f2a7776e14e54b
- Quelldatensatz
- uspto-grants-1992_11
- Patentnummer
- US05162285
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