Tributylamine → 4-(Chloromethyl)benzyltri-n-butylammonium chloride

HRID 375023

Reaktionsgleichung

Reaktionsgleichung von HRID 375023
[CH2:1]([N:5]([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].[Cl:14][CH2:15][C:16]1[CH:21]=[CH:20][C:19]([CH2:22][Cl:23])=[CH:18][CH:17]=1>CO>[Cl-:14].[Cl:23][CH2:22][C:19]1[CH:20]=[CH:21][C:16]([CH2:15][N+:5]([CH2:6][CH2:7][CH2:8][CH3:9])([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:1][CH2:2][CH2:3][CH3:4])=[CH:17][CH:18]=1

Komponenten

4

Edukt 2

HCID 7622TributylamineHCID 12171alpha,alpha'-Dichloro-p-xylene

Produkt 1

HCID 867489774-(Chloromethyl)benzyltri-n-butylammonium chloride

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

A mixture of tri-n-butylamine (6 g, 32.2 mmol) and α,α'-dichloro-p-xylene (8.0 g, 46.0 mmol) in methanol (50 mL) was refluxed for 15 h after which time TLC examination showed completion of the reaction. Methanol was removed under reduced pressure to give an oily residue. The colorless oil was washed several times with toluene and hexane and then dried. The product obtained was used without further purification.

Aufarbeitung

  1. temperaturewas refluxed for 15 h after which time TLC examination
  2. customcompletion of the reaction
  3. customMethanol was removed under reduced pressure
  4. customto give an oily residue
  5. washThe colorless oil was washed several times with toluene and hexane
  6. customdried
  7. customThe product obtained
  8. customwas used without further purification

Quellen und Nachweise

ORD-Eintrag
ord-bce55896643248c297bd6e26e3da7f7e
Quelldatensatz
uspto-grants-1996_01
Patentnummer
US05484556

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