Acrylic Acid → Prop-2-enoic acid--prop-2-enal (1/1)

HRID 37735

Reaktionsgleichung

Reaktionsgleichung von HRID 37735
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].C(C=C)=O>CO>[CH:1]([CH:2]=[CH2:3])=[O:4].[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3]

Komponenten

4

Edukt 2

HCID 6581Acrylic Acid2×HCID 7847Acrolein2×

Produkt 1

HCID 3084492Prop-2-enoic acid--prop-2-enal (1/1)

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

Control drug: (acrylic acid:acrolein (mol)=95:5): 3.25 g freshly distilled acrolein and 79.27 g freshly distilled acrylic acid were added into a three-port flask with 520 ml absolute methanol, purged with nitrogen, 4.74 g benzoyl peroxide was added, and the solution was stirred and heated to reflux under nitrogen for 50 h. The reaction solution became a yellowish viscous liquid, which was dried under vacuum at 50-100° C. for 24 hours to form poly (acrolein-acrylic acid) named A3.

Aufarbeitung

  1. custompurged with nitrogen, 4.74 g benzoyl peroxide
  2. additionwas added
  3. temperatureheated
  4. temperatureto reflux under nitrogen for 50 h
  5. customwas dried under vacuum at 50-100° C. for 24 hours

Quellen und Nachweise

ORD-Eintrag
ord-5a15d92a442f4a9a8f8753420daea0f0
Quelldatensatz
uspto-grants-2013_09
Patentnummer
US08524216B2

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