Nitrogen → Di-tert-butyl ether

HRID 378771

Reaktionsgleichung

Reaktionsgleichung von HRID 378771
[C:1]([OH:5])([CH3:4])([CH3:3])[CH3:2].C(O)CCCCC.N#N.[C:15](OCCCCCC)([CH3:18])([CH3:17])[CH3:16]>>[C:1]([O:5][C:15]([CH3:18])([CH3:17])[CH3:16])([CH3:4])([CH3:3])[CH3:2]

Komponenten

5

Edukt 4

HCID 947NitrogenHCID 6386tert-ButanolHCID 81031-Hexanol2×HCID 547839Hexyl t-butyl ether

Produkt 1

HCID 22541Di-tert-butyl ether

Versuchsvorschrift

300 mmoles of t-butanol, 100 mmoles of 1-hexanol and 2.5 g of Ti-Si-catalyst powder are stirred in a 100 ml autoclave at a pressure of 40 bar N2 and a temperature of 150° C. over a period of 17 h, 17% of n hexanol were converted into hexyl t-butyl ether with a selectivity of 90%.

Quellen und Nachweise

ORD-Eintrag
ord-c4b88dc8fc2f43d4a6be06585468b591
Quelldatensatz
uspto-grants-2001_10
Patentnummer
US06297180B1

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