Iodine → Muconic Acid

HRID 385206

Reaktionsgleichung

Reaktionsgleichung von HRID 385206
[C:1]([OH:10])(=[O:9])/[CH:2]=[CH:3]\[CH:4]=[CH:5]\[C:6]([OH:8])=[O:7].II>CO>[C:1]([OH:10])(=[O:9])/[CH:2]=[CH:3]/[CH:4]=[CH:5]/[C:6]([OH:8])=[O:7]

Komponenten

4

Edukt 2

HCID 807IodineHCID 5280614(2E,4Z)-2,4-Hexadienedioic acid

Produkt 1

HCID 5356793Muconic AcidAusbeute 62 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

cis,trans-Muconic acid (105 mg, 0.739 mmol) is dissolved in methanol (10 mL) at room temperature and a crystal of iodine (26 mg, 0.102 mmol) is added. The reaction mixture is allowed to stir at room temperature for 24 hours. The precipitate is filtered, washed with ice-cold acetonitrile and dried under reduced pressure to yield 65 mg of trans,trans-muconic acid, a 62 percent yield.

Aufarbeitung

  1. filtrationThe precipitate is filtered
  2. washwashed with ice-cold acetonitrile
  3. customdried under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-1f568005e5cf4956a6ba2effee60c353
Quelldatensatz
uspto-grants-2013_02
Patentnummer
US08367858B2

Verknüpfte Notizen

Wird geladen…