Iodine → Muconic Acid

HRID 385207

Reaktionsgleichung

Reaktionsgleichung von HRID 385207
[C:1]([OH:10])(=[O:9])/[CH:2]=[CH:3]\[CH:4]=[CH:5]\[C:6]([OH:8])=[O:7].II>C(O)C>[C:1]([OH:10])(=[O:9])/[CH:2]=[CH:3]/[CH:4]=[CH:5]/[C:6]([OH:8])=[O:7]

Komponenten

4

Edukt 2

HCID 807IodineHCID 5280614(2E,4Z)-2,4-Hexadienedioic acid

Produkt 1

HCID 5356793Muconic AcidAusbeute 67 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

cis,trans-Muconic acid (105 mg, 0.739 mmol) is dissolved in ethanol (10 mL) at room temperature and a crystal of iodine (13 mg, 0.05 mmol) is added. The reaction mixture is allowed to stir at room temperature for 24 hour. The precipitate is filtered, washed with acetonitrile and dried under reduced pressure to yield 70 mg of trans,trans-muconic acid, a 67 percent yield.

Aufarbeitung

  1. filtrationThe precipitate is filtered
  2. washwashed with acetonitrile
  3. customdried under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-cfce37146f754218bd32a6185afc620b
Quelldatensatz
uspto-grants-2013_02
Patentnummer
US08367858B2

Verknüpfte Notizen

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