Iodine → Muconic Acid

HRID 385208

Reaktionsgleichung

Reaktionsgleichung von HRID 385208
[C:1]([OH:10])(=[O:9])/[CH:2]=[CH:3]\[CH:4]=[CH:5]\[C:6]([OH:8])=[O:7].II>C(O)CC>[C:1]([OH:10])(=[O:9])/[CH:2]=[CH:3]/[CH:4]=[CH:5]/[C:6]([OH:8])=[O:7]

Komponenten

4

Edukt 2

HCID 807IodineHCID 5280614(2E,4Z)-2,4-Hexadienedioic acid

Produkt 1

HCID 5356793Muconic AcidAusbeute 73 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 10311-PropanolLösungsmittel

Versuchsvorschrift

cis,trans-Muconic acid (103 mg, 0.725 mmol) is dissolved in n-propanol (10 mL) at room temperature and a crystal of iodine (10 mg, 0.04 mmol) is added. The reaction mixture is allowed to stir at room temperature for 24 hours. The precipitate is filtered, washed with acetonitrile and dried under reduced pressure to yield 75 mg of trans,trans-muconic acid, a 73 percent yield.

Aufarbeitung

  1. filtrationThe precipitate is filtered
  2. washwashed with acetonitrile
  3. customdried under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-43b6087262e946d986e929fdc93548e2
Quelldatensatz
uspto-grants-2013_02
Patentnummer
US08367858B2

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