1,4-Cyclohexadiene-1,4-dicarboxylic acid, 2,5-bis(phenylamino)-, 1,4-dimethyl ester → Dimethyl 2,5-dianilinobenzene-1,4-dicarboxylate

HRID 399185

Reaktionsgleichung

Reaktionsgleichung von HRID 399185
[CH3:1][O:2][C:3](=[O:30])[C:4]1[CH2:13][C:12]([NH:14][C:15]2[CH:20]=[CH:19][C:18](Cl)=[CH:17][CH:16]=2)=[C:7]([C:8]([O:10][CH3:11])=[O:9])[CH2:6][C:5]=1[NH:22][C:23]1[CH:28]=[CH:27][C:26](Cl)=[CH:25][CH:24]=1.COC(=O)C1CC(NC2C=CC=CC=2)=C(C(OC)=O)CC=1NC1C=CC=CC=1>>[CH3:11][O:10][C:8](=[O:9])[C:7]1[CH:6]=[C:5]([NH:22][C:23]2[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=2)[C:4]([C:3]([O:2][CH3:1])=[O:30])=[CH:13][C:12]=1[NH:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1

Komponenten

3

Edukt 2

HCID 786101,4-Cyclohexadiene-1,4-dicarboxylic acid, 2,5-bis(phenylamino)-, 1,4-dimethyl esterHCID 147459351,4-Cyclohexadiene-1,4-dicarboxylic acid, 2,5-bis((4-chlorophenyl)amino)-, 1,4-dimethyl ester

Produkt 1

HCID 19963874Dimethyl 2,5-dianilinobenzene-1,4-dicarboxylate

Versuchsvorschrift

Example 13 was repeated except that the 2,5-di(p-chloroanilino)-3,6-dihydroterephthalic acid dimethyl ester used in Example 13 was replaced with 7.56 parts of 2,5-dianilino-3,6-dihydroterephthalic acid dimethyl ester, to give 6.88 parts (98.9% of the theoretical yield) of 2,5-dianilinoterephthalic acid dimethyl ester.

Aufarbeitung

  1. customto give 6.88 parts (98.9% of the

Quellen und Nachweise

ORD-Eintrag
ord-1faff77c9c974f94a187fc2cf48810e6
Quelldatensatz
uspto-grants-1998_10
Patentnummer
US05817817

Verknüpfte Notizen

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