2-(Methylthio)aniline → 5-n-Propylthiooxindole

HRID 414410

Reaktionsgleichung

Reaktionsgleichung von HRID 414410
[CH3:1][S:2][C:3]1[CH:9]=[CH:8][CH:7]=[CH:6][C:4]=1[NH2:5].[CH2:10]([S:14][C:15]1[CH:21]=[CH:20][CH:19]=[CH:18][C:16]=1[NH2:17])[CH2:11][CH2:12]C.[CH2:22]([S:25][C:26]1[CH:32]=[CH:31][C:29]([NH2:30])=[CH:28][CH:27]=1)[CH2:23]C>>[CH3:22][C:9]1[CH:8]=[CH:7][CH:6]=[C:4]2[C:3]=1[CH2:11][C:10](=[S:14])[NH:5]2.[CH3:1][C:19]1[CH:18]=[C:16]2[C:15]([CH2:23][C:22](=[S:25])[NH:17]2)=[CH:21][CH:20]=1.[CH2:10]([C:26]1[CH:27]=[C:28]2[C:29](=[CH:31][CH:32]=1)[NH:30][C:3](=[S:2])[CH2:4]2)[CH2:11][CH3:12]

Komponenten

6

Edukt 3

HCID 763372-(Methylthio)anilineHCID 45559974-(Propylthio)anilineHCID 103299602-Butylmercaptoaniline

Produkt 3

HCID 212820345-n-PropylthiooxindoleHCID 212820706-MethylthiooxindoleHCID 212820744-Methylthiooxindole

Versuchsvorschrift

4-Methylthiooxindole and 6-methylthiooxindole are prepared according to the procedure of U.S. Pat. No. 4,006,161. 7-Methylthio and 7-n-butylthiooxindoles are prepared by using the same procedure starting with 2-methylthioaniline and 2-n-butylthioaniline, respectively. 5-n-Propylthiooxindole is prepared by the same synthetic route starting with 4-n-propylthioaniline.

Quellen und Nachweise

ORD-Eintrag
ord-fc0ff95e0b4342869d38bb7082edbab7
Quelldatensatz
uspto-grants-1988_12
Patentnummer
US04791129

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