Formaldehyde → (1R,5R)-10-hydroxymethyl-2-pinene

HRID 414572

Reaktionsgleichung

Reaktionsgleichung von HRID 414572
[CH3:1][C:2]1([CH3:10])[CH:8]2[CH2:9][CH:3]1[CH2:4][CH2:5][C:6]2=[CH2:7].[CH2:11]=[O:12]>>[OH:12][CH2:11][CH2:7][C:6]1[C@@H:8]2[CH2:9][C@@H:3]([CH2:4][CH:5]=1)[C:2]2([CH3:10])[CH3:1]

Komponenten

3

Edukt 2

HCID 712FormaldehydeHCID 14896Beta-Pinene

Produkt 1

HCID 6978972(1R,5R)-10-hydroxymethyl-2-pinene

Versuchsvorschrift

A mixture of β-pinene (32 ml) and paraformaldehyde (4 g) in sealed tube was reacted for 18 hrs at 180° C. The reaction solution was distilled to give the title compound (15.5 g) having the following physical data:

Aufarbeitung

  1. customwas reacted for 18 hrs at 180° C
  2. distillationThe reaction solution was distilled

Quellen und Nachweise

ORD-Eintrag
ord-e68a368eafa94ffeb9e2294b9496f4e5
Quelldatensatz
uspto-grants-1988_12
Patentnummer
US04792550

Verknüpfte Notizen

Wird geladen…