1-Bromo-4-methoxybutane → Phenazine

HRID 41803

Reaktionsgleichung

Reaktionsgleichung von HRID 41803
O[C:2]1[C:15]2[C:6](=[N:7][C:8]3[C:13]([N:14]=2)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1.[CH3:16][O:17][CH2:18][CH2:19]CCBr>>[CH:12]1[C:13]2[C:8](=[N:7][C:6]3[C:15]([N:14]=2)=[CH:2][CH:3]=[CH:4][CH:5]=3)[CH:9]=[CH:10][CH:11]=1.[CH:12]1[C:13]2[C:8](=[N:7][C:6]3[C:15]([N:14]=2)=[CH:2][CH:3]=[CH:4][CH:5]=3)[CH:9]=[CH:10][CH:11]=1.[CH3:19][CH2:18][O:17][CH2:16][CH3:2]

Komponenten

4

Edukt 2

HCID 5211681-Bromo-4-methoxybutaneHCID 1354126481-Phenazinol

Produkt 2

HCID 4757PhenazineHCID 67351390Ethoxyethane;phenazine

Versuchsvorschrift

Scheme 6 illustrates the synthesis of N-ethyl phenazine 1-hydroxybutyl methyl ether. The phenazine ether (21) is prepared by the alkylation of the 1-hydroxyphenazine (1) with 4-methoxybutylbromide (Aldrich Chemical Company, USA) to give phenazine derivative (21). N-ethyl phenazine (22) is prepared by reaction of compound (21) with diethyl sulfate in the presence of potassium carbonate.

Quellen und Nachweise

ORD-Eintrag
ord-e25732e929014617bb8a9f0d336395cb
Quelldatensatz
uspto-grants-2013_09
Patentnummer
US08535511B2

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