1,4-Dioxane → HCID 86647269, Verbindung

HRID 421544

Reaktionsgleichung

Reaktionsgleichung von HRID 421544
[CH3:1][N:2]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH3:3].[CH3:14][C:15]1[CH:20]=[CH:19][C:18]([S:21]([O:24]CCOC)(=[O:23])=[O:22])=[CH:17][CH:16]=1.O1[CH2:34][CH2:33][O:32][CH2:31]C1>>[CH3:14][C:15]1[CH:16]=[CH:17][C:18]([S:21]([O-:24])(=[O:23])=[O:22])=[CH:19][CH:20]=1.[CH3:31][O:32][CH2:33][CH2:34][N+:2]([CH3:1])([CH3:3])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

Komponenten

4

Edukt 3

HCID 312751,4-DioxaneHCID 70711N,N-Dimethyl-N-decylamineHCID 86977Ethanol, 2-methoxy-, 1-(4-methylbenzenesulfonate)

Produkt 1

HCID 86647269HCID 86647269, Verbindung

Reaktionsbedingungen

Temperatur
75 °C

Versuchsvorschrift

The reaction was performed in an inert atmosphere. N,N-dimethyldecylamine (16.21 mmol, 3.7 g) and 2-methoxyethyl 4-methylbenzenesulfonate (16.21 mmol, 3.71 g) prepared in the previous step were mixed together in a round bottom flask. Dioxane (10 mL) was added to the reaction mixture. The reaction mixture was heated at 75° C. for 18 hours. The solvent was removed by a rotoevaporator, and the remaining viscous liquid was cooled and dried. A white solid was obtained as N-(2-methoxyethyl)-N,N-dimethyldecan-1-aminium 4-methylbenzenesulfonate. The reaction was also performed in absence of any solvent and the desired product was obtained in quantitative yield. Similarly other surfactants were synthesized following the above-mentioned method.

Aufarbeitung

  1. additionwere mixed together in a round bottom flask
  2. customThe solvent was removed by a rotoevaporator
  3. temperaturethe remaining viscous liquid was cooled
  4. customdried

Quellen und Nachweise

ORD-Eintrag
ord-b50ca79a8c0e488699eff2ae8bdf061f
Quelldatensatz
uspto-grants-2012_01
Patentnummer
US08101556B2

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