HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Dimethylformamide → [2-(5-Fluoro-2,4-dinitro-phenyl)-vinyl]-dimethyl-amine
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Dimethylformamide | HCID 6228 | — |
| Edukt | Dimethylformamide dimethyl acetal | HCID 78373 | — |
| Edukt | 1-Fluoro-5-methyl-2,4-dinitrobenzene | HCID 520705 | — |
| Lösungsmittel | Water | HCID 962 | — |
| Produkt | [2-(5-Fluoro-2,4-dinitro-phenyl)-vinyl]-dimethyl-amine | HCID 57060726 | 63% |
Reaktionsbedingungen
| Temperatur | 100 °C |
|---|
Reaktionsschritte
A mixture of 1-fluoro-5-methyl-2,4-dinitro-benzene (10 g, 50 mmol), dimethoxymethyl-dimethylamine (11.9 g, 100 mmol) and DMF (50 mL) was heated at 100° C. for 4 h. The solution was cooled and poured into water. The red precipitate was collected via filtration, washed with water adequately and dried to give [2-(5-fluoro-2,4-dinitro-phenyl)-vinyl]-dimethyl-amine (8 g, 63%).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US08101767B2 |
| Quelldatensatz | uspto-grants-2012_01 |
| ORD ID | ord-58383551095046d48a529bb093c4cd24 |
| Quellennotiz | uspto-grants-2012_01 |