2-Bromo-5-methoxybenzoic acid → 2-Bromo-5-methoxy-1-(methoxymethoxymethyl)benzene
Reaktionsgleichung
[Br:1][C:2]1[CH:10]=[CH:9][C:8]([O:11][CH3:12])=[CH:7][C:3]=1[C:4]([OH:6])=O.BrC1C=CC(Cl)=CC=1[CH2:21][O:22][CH2:23]OC>>[Br:1][C:2]1[CH:10]=[CH:9][C:8]([O:11][CH3:12])=[CH:7][C:3]=1[CH2:4][O:6][CH2:21][O:22][CH3:23]Komponenten
3
Versuchsvorschrift
This compound was made from 2-bromo-5-methoxybenzoic acid in the same manner as compound 18d: 1H NMR (300 MHz, DMSO-d6): δ 3.30 (s, 1H), 3.74 (s, 3H), 4.50 (s, 2H), 4.69 (s, 2H), 6.83 (dd, J=8.8, 2.9 Hz, 1H), 7.40 (d, J=2.9 Hz, 1H), 7.48 (d, J=8.8 Hz, 1H).
Quellen und Nachweise
- ORD-Eintrag
- ord-34359cc606f04c659ed8d0de501cd524
- Quelldatensatz
- uspto-grants-2012_01
- Patentnummer
- US08106031B2
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