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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 429607Erstellt: 24. Oktober 2026

Diethyl Ether → trans-Stilbene

https://huagongshe.com/de/reaction/429607

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktDiethyl EtherHCID 3283—
EduktHexadecaneHCID 11006—
EduktDecaneHCID 15600—
Produkt1,1-DiphenylethyleneHCID 1074013,2%
Produkttrans-StilbeneHCID 63808886,5%
Produktcis-StilbeneHCID 53567850,3%

Reaktionsschritte

After the reaction, the GC standards n-decane and n-hexadecane are added, and 3 ml of diethyl ether is added to the mixture. After filtering off the solids, the filtrate is examined by gas chromatography: With 78.5% conversion of Cl-benzene, an 80% yield of Heck products (86.5% trans-stilbene, 0.3% cis-stilbene, and 13.2% 1,1-diphenylethene) is obtained.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS06316675B1
Quelldatensatzuspto-grants-2001_11
ORD IDord-f3a777079160482a87d4855a87394aa2
Quellennotizuspto-grants-2001_11