HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Diethyl Ether → trans-Stilbene
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Diethyl Ether | HCID 3283 | — |
| Edukt | Hexadecane | HCID 11006 | — |
| Edukt | Decane | HCID 15600 | — |
| Produkt | 1,1-Diphenylethylene | HCID 10740 | 13,2% |
| Produkt | trans-Stilbene | HCID 638088 | 86,5% |
| Produkt | cis-Stilbene | HCID 5356785 | 0,3% |
Reaktionsschritte
After the reaction, the GC standards n-decane and n-hexadecane are added, and 3 ml of diethyl ether is added to the mixture. After filtering off the solids, the filtrate is examined by gas chromatography: With 78.5% conversion of Cl-benzene, an 80% yield of Heck products (86.5% trans-stilbene, 0.3% cis-stilbene, and 13.2% 1,1-diphenylethene) is obtained.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06316675B1 |
| Quelldatensatz | uspto-grants-2001_11 |
| ORD ID | ord-f3a777079160482a87d4855a87394aa2 |
| Quellennotiz | uspto-grants-2001_11 |