(R)-(-)-1-Methyheptyl 4-Methoxycarbonyloxybenzoate → (R)-(-)-1-Methylheptyl 4-Hydroxybenzoate

HRID 433043Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 433043
COC([O:5][C:6]1[CH:22]=[CH:21][C:9]([C:10]([O:12][C@H:13]([CH3:20])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])=[O:11])=[CH:8][CH:7]=1)=O>C(O)C.N>[OH:5][C:6]1[CH:22]=[CH:21][C:9]([C:10]([O:12][C@H:13]([CH3:20])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])=[O:11])=[CH:8][CH:7]=1

Komponenten

4

Edukt 1

HCID 70010659(R)-(-)-1-Methyheptyl 4-Methoxycarbonyloxybenzoate

Produkt 1

HCID 13980124(R)-(-)-1-Methylheptyl 4-Hydroxybenzoate

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 222AmmoniaLösungsmittelHCID 702EthanolLösungsmittel

Versuchsvorschrift

Compound 3 (11.6 g, 38 mmol) in ethanol (200 ml) and aqueous ammonia (50 ml) was stirred overnight. The solvents were removed in vacuo and the resulting colourless oil was purified by column chromatography (ethyl acetate) on silica.

Aufarbeitung

  1. customThe solvents were removed in vacuo
  2. customthe resulting colourless oil was purified by column chromatography (ethyl acetate) on silica

Quellen und Nachweise

ORD-Eintrag
ord-b0f16c51de7747f9ab721b7f67c9b915
Quelldatensatz
uspto-grants-2003_12
Patentnummer
US06666989B1

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