Thionyl Chloride → 3-Methyl-6-(phenylthio)-benzyl chloride

HRID 435665Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 435665
[CH3:1][C:2]1[CH:3]=[C:4]([C:7]([S:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:8][CH:9]=1)[CH2:5]O.S(Cl)([Cl:19])=O>C1C=CC=CC=1>[CH3:1][C:2]1[CH:3]=[C:4]([C:7]([S:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:8][CH:9]=1)[CH2:5][Cl:19]

Komponenten

4

Edukt 2

HCID 24386Thionyl ChlorideHCID 12539099HCID 12539099, Verbindung

Produkt 1

HCID 125391003-Methyl-6-(phenylthio)-benzyl chloride

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 241BenzeneLösungsmittel

Versuchsvorschrift

570.7 g of 3-methyl-6-(phenylthio)-benzyl alcohol are dissolved in 1.5 litres of benzene and heated under reflux. There are added dropwise thereto within 45 minutes 352 ml of thionyl chloride and the mixture is boiled for a further 90 minutes. Then the mixture is concentrated under reduced pressure and there is obtained 3-methyl-6-(phenylthio)-benzyl chloride as a red-brown oil.

Aufarbeitung

  1. temperatureheated
  2. temperatureunder reflux
  3. additionThere are added dropwise
  4. concentrationThen the mixture is concentrated under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-5c9ac29b07614bd8afa424a4ace031fa
Quelldatensatz
uspto-grants-1977_02
Patentnummer
US04006144

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