Nitric Acid → m-Nitrobenzenephosphonous acid

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Reaktionsgleichung

[C:1]1([P:7]([OH:9])[OH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.S(=O)(=O)(O)O.[N+:15]([O-])([OH:17])=[O:16]>>[N+:15]([C:3]1[CH:2]=[C:1]([P:7]([OH:9])[OH:8])[CH:6]=[CH:5][CH:4]=1)([O-:17])=[O:16]

Komponenten

Edukt 3

HCID 944Nitric Acid

HCID 1118Sulfuric Acid

HCID 72903Phenylphosphinic acid

Produkt 1

HCID 21431775m-Nitrobenzenephosphonous acid

Versuchsvorschrift

reacting benzenephosphonous acid in a sulfuric acid medium under nitrating conditions by the dropwise addition of nitric acid at a temperature of about 0° C. to about 5° C. to form m-nitrobenzenephosphonous acid in a reaction mixture;

Quellen und Nachweise

ORD-Eintrag: ord-14b9c7d9ecd64990bf6cc490b8bde3a2
Quelldatensatz: uspto-grants-1977_06
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04028403

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