Ethyl formate → Hydrazinecarboxaldehyde, 2-(4-nitrophenyl)-

HRID 437499Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 437499
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([NH:10][NH2:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].[CH:12]([O-])=[O:13].[Na+].C(OCC)=O>C(O)C.C(O)(=O)/C=C/C(O)=O>[CH:12]([NH:11][NH:10][C:7]1[CH:6]=[CH:5][C:4]([N+:1]([O-:3])=[O:2])=[CH:9][CH:8]=1)=[O:13]

Komponenten

6

Edukt 3

HCID 8025Ethyl formateHCID 2723810Sodium FormateHCID 3310889(4-Nitrophenyl)hydrazine

Produkt 1

HCID 5008489Hydrazinecarboxaldehyde, 2-(4-nitrophenyl)-

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 702EthanolLösungsmittelHCID 444972Fumaric AcidLösungsmittel

Versuchsvorschrift

4-Nitrophenylhydrazine (9.2 g, 0.06 mole), sodium formate (4.08 g, 0.06 mole), and ethyl formate (148 g, 2.00 moles) were mixed in ethanol (40 ml) and fumaric acid (30 ml). The mixture was heated on a steam bath; the volume of the mixture was reduced to approximately 100 ml by continued boiling. The hydrazide product crystallized out of the concentrated reaction mixture upon cooling. The product was filtered off, washed with ethanol, and dried. Yield 10.2 g (94%), m.p. 183°-185° C.

Aufarbeitung

  1. temperatureThe mixture was heated on a steam bath
  2. customThe hydrazide product crystallized out of the concentrated reaction mixture
  3. temperatureupon cooling
  4. filtrationThe product was filtered off
  5. washwashed with ethanol
  6. customdried

Quellen und Nachweise

ORD-Eintrag
ord-322c1f8a52784c6eac53463650da8b2b
Quelldatensatz
uspto-grants-1977_06
Patentnummer
US04031127

Notizen zur Reaktion

Wird geladen…