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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 441759Erstellt: 25. Oktober 2026

Ethylene glycol diacetate → 2,8-Dimethyldibenzofuran

https://huagongshe.com/reaction/441759

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktEthylene glycol diacetateHCID 8121—
EduktAcetylacetoneHCID 31261—
EduktBenzene, 1,1'-oxybis[4-methyl-HCID 74098—
KatalysatorPalladium(II) propionateHCID 11459426—
Produkt2,8-DimethyldibenzofuranHCID 63931918,7%

Reaktionsschritte

This example was carried out under the same conditions as in Example 1 except that 15.0 g of 4,4'-dimethyldiphenyl ether, 0.038 g (0.15 m. mole) of palladium propionate, 0.015 g (0.15 m. mole) of acetylacetone and 5 ml of ethylene glycol diacetate were employed. As a result, 2.78 g (14 m. moles) of 2,8-dimethyldibenzofuran and 0.78 g (2.0 m. moles) of the dimer also obtained.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS04042603
Quelldatensatzuspto-grants-1977_08
ORD IDord-bbfe23b2dffb41458a1fb8767edbb62f
Quellennotizuspto-grants-1977_08