Water → 1-(Hydroxymethyl)cyclohexan-1-ol

HRID 442049

Reaktionsgleichung

Reaktionsgleichung von HRID 442049
N[CH2:2][C:3]1([OH:9])[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4]1.[OH2:10]>>[OH:10][CH2:2][C:3]1([OH:9])[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4]1

Komponenten

3

Edukt 2

HCID 962WaterHCID 776141-(Aminomethyl)cyclohexan-1-ol

Produkt 1

HCID 2512591-(Hydroxymethyl)cyclohexan-1-ol

Versuchsvorschrift

Compounds of this type may be prepared from isophorone utilizing the methods described in U.S. Pat. Nos. 3,270,044 and 3,352,913 to form an amino methyl cyclohexanol which is then reacted with a carboxylic acid in a fusion cook by heating stoichiometric quantities of the amine and the acid until molten and stirring the molten mixture with a nitrogen sweep to drive off water vapor. The progress of the reaction is stopped when an acid number just below theoretical is obtained. Similarly, the carboxylate derivative can be formed from a hydroxymethyl cyclohexanol.

Aufarbeitung

  1. custombelow theoretical is obtained

Quellen und Nachweise

ORD-Eintrag
ord-bdd398d5c3704a7b95a78d2539cfe0b5
Quelldatensatz
uspto-grants-1977_08
Patentnummer
US04044033

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