Benzaldehyde → Benzal chloride

HRID 442070

Reaktionsgleichung

Reaktionsgleichung von HRID 442070
[CH:1](=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Cl-:9].[Cl-:10].C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1>>[CH:1]([Cl:10])([Cl:9])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Komponenten

3

Edukt 2

HCID 240BenzaldehydeHCID 13797396Triphenylphosphane dichloride

Produkt 1

HCID 7411Benzal chlorideAusbeute 45 %

Versuchsvorschrift

Furthermore, it is known from Liebig's Annalen der Chemie, Volume 626, pages 26 to 34 (1959) to react benzaldehyde with triphenylphosphine dichloride to give benzal chloride, but the yield is only 59%. When cyclohexanone is reacted with triphenylphosphine dichloride in the presence of an equimolar amount of triethylamine it is not the corresponding geminal dihalide which is obtained but 1-chlorocyclohex-1-ene in 45% yield (loc. cit., page 33).

Quellen und Nachweise

ORD-Eintrag
ord-72beb27f2df144ba840b75f81578cf24
Quelldatensatz
uspto-grants-1977_08
Patentnummer
US04044060

Verknüpfte Notizen

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