Hydrochloric Acid → 2,6-Di-tert-butyl-4-(chloromethyl)phenol

HRID 444107

Reaktionsgleichung

Reaktionsgleichung von HRID 444107
[OH:1][C:2]1[C:9]([C:10]([CH3:13])([CH3:12])[CH3:11])=[CH:8][C:5]([CH2:6]O)=[CH:4][C:3]=1[C:14]([CH3:17])([CH3:16])[CH3:15].[ClH:18]>CCCCCC>[OH:1][C:2]1[C:9]([C:10]([CH3:13])([CH3:12])[CH3:11])=[CH:8][C:5]([CH2:6][Cl:18])=[CH:4][C:3]=1[C:14]([CH3:17])([CH3:16])[CH3:15]

Komponenten

4

Edukt 2

HCID 313Hydrochloric AcidHCID 6929Butylated hydroxymethylphenol

Produkt 1

HCID 123786012,6-Di-tert-butyl-4-(chloromethyl)phenol

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8058HexaneLösungsmittel

Versuchsvorschrift

176 grams of 4-hydroxy-3,5-di-tert-butyl-benzyl alcohol was slurried in 350 ml of hexane. 240 cc of concentrated HCl was added to the slurry and stirred overnight. The two phases were allowed to separate and the hexane phase washed twice with water. The dried hexane was then extracted with magnesium sulfate and filtered. Rotofilm evaporation yielded 168 grams of product--a pungent yellow liquid.

Aufarbeitung

  1. customto separate
  2. washthe hexane phase washed twice with water
  3. extractionThe dried hexane was then extracted with magnesium sulfate
  4. filtrationfiltered
  5. customRotofilm evaporation

Quellen und Nachweise

ORD-Eintrag
ord-0c6429c18bae40c796f71c081f89e807
Quelldatensatz
uspto-grants-1981_04
Patentnummer
US04263154

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