2-(4-bromophenoxy)-N,N-diethylethanamine → Diethyl({2-[4-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy]ethyl})amine

HRID 449143

Reaktionsgleichung

Reaktionsgleichung von HRID 449143
Br[C:2]1[CH:15]=[CH:14][C:5]([O:6][CH2:7][CH2:8][N:9]([CH2:12][CH3:13])[CH2:10][CH3:11])=[CH:4][CH:3]=1.[CH3:16][C:17]1([CH3:38])[C:21]([CH3:23])([CH3:22])[O:20][B:19](C2C=CC(OC3C=CC=CC=3)=CC=2C)[O:18]1>>[CH2:10]([N:9]([CH2:12][CH3:13])[CH2:8][CH2:7][O:6][C:5]1[CH:14]=[CH:15][C:2]([B:19]2[O:20][C:21]([CH3:23])([CH3:22])[C:17]([CH3:38])([CH3:16])[O:18]2)=[CH:3][CH:4]=1)[CH3:11]

Komponenten

3

Edukt 2

HCID 4239532-(4-bromophenoxy)-N,N-diethylethanamineHCID 227364244,4,5,5-Tetramethyl-2-(2-methyl-4-phenoxyphenyl)-1,3,2-dioxaborolane

Produkt 1

HCID 58354678Diethyl({2-[4-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy]ethyl})amine

Versuchsvorschrift

Prepared from [2-(4-bromo-phenoxy)-ethyl]-diethyl-amine according to general Method I for borylation described above for preparation of 4,4,5,5-tetramethyl-2-(2-methyl-4-phenoxy-phenyl)-[1,3,2]dioxaborolane.

Quellen und Nachweise

ORD-Eintrag
ord-974da08403e04a9a8dbacaa535469ebd
Quelldatensatz
uspto-grants-2013_07
Patentnummer
US08481733B2

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