[2-(3-Bromophenoxy)ethyl]dimethylamine → Dimethyl((2-(3-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)ethyl))amine
Reaktionsgleichung
Br[C:2]1[CH:3]=[C:4]([CH:11]=[CH:12][CH:13]=1)[O:5][CH2:6][CH2:7][N:8]([CH3:10])[CH3:9].[CH3:14][C:15]1([CH3:36])[C:19]([CH3:21])([CH3:20])[O:18][B:17](C2C=CC(OC3C=CC=CC=3)=CC=2C)[O:16]1>>[CH3:9][N:8]([CH3:10])[CH2:7][CH2:6][O:5][C:4]1[CH:11]=[CH:12][CH:13]=[C:2]([B:17]2[O:18][C:19]([CH3:21])([CH3:20])[C:15]([CH3:36])([CH3:14])[O:16]2)[CH:3]=1Komponenten
3
Versuchsvorschrift
Prepared from [2-(3-bromo-phenoxy)-ethyl]-dimethyl-amine according to general Method I for borylation described above for preparation of 4,4,5,5-tetramethyl-2-(2-methyl-4-phenoxy-phenyl)-[1,3,2]dioxaborolane.
Quellen und Nachweise
- ORD-Eintrag
- ord-9b28d0d8b9ef4c61a7003cfbddc3b0d3
- Quelldatensatz
- uspto-grants-2013_07