Triphenylphosphine → (2,5-Dimethyl-3-thenyl)triphenylphosphonium chloride

HRID 460953

Reaktionsgleichung

Reaktionsgleichung von HRID 460953
[C:1]1([P:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:20][C:21]1[S:22][C:23]([CH3:28])=[CH:24][C:25]=1[CH2:26][Cl:27]>C1(C)C=CC=CC=1>[Cl-:27].[CH3:20][C:21]1[S:22][C:23]([CH3:28])=[CH:24][C:25]=1[CH2:26][P+:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1

Komponenten

4

Edukt 2

HCID 11776TriphenylphosphineHCID 128752613-(Chloromethyl)-2,5-dimethylthiophene

Produkt 1

HCID 20285688(2,5-Dimethyl-3-thenyl)triphenylphosphonium chloride

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1140TolueneLösungsmittel

Versuchsvorschrift

Triphenylphosphine (11.8 g.) and 7.0 g. of 2,5-dimethyl-3-chloromethylthiophene were dissolved in 100 ml. of toluene. The mixture was refluxed overnight under argon, cooled to room temperature and the precipitated white phosphonium salt was collected by filtration, washed several times with cold benzene and dried at 80° C. under high vacuum. The resulting (2,5-dimethyl-3-thenyl)-triphenylphosphonium chloride has a m.p. 246°-250° C.

Aufarbeitung

  1. temperatureThe mixture was refluxed overnight under argon
  2. filtrationthe precipitated white phosphonium salt was collected by filtration
  3. washwashed several times with cold benzene
  4. customdried at 80° C. under high vacuum

Quellen und Nachweise

ORD-Eintrag
ord-77bac11b374d4b569275e985baa2db7f
Quelldatensatz
uspto-grants-1977_12
Patentnummer
US04061656

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