m-Chloroperbenzoic acid → 2-Octyl-4,5-dichloro-3-isothiazolidinone 1,1-dioxide

HRID 461366Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 461366
[CH2:1]([N:9]1[C:13](=[O:14])[CH:12]([Cl:15])[CH:11]([Cl:16])[S:10]1=[O:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].ClC1C=CC=C(C(OO)=[O:26])C=1>C(Cl)(Cl)Cl>[CH2:1]([N:9]1[C:13](=[O:14])[CH:12]([Cl:15])[CH:11]([Cl:16])[S:10]1(=[O:26])=[O:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Komponenten

4

Edukt 2

HCID 70297m-Chloroperbenzoic acidHCID 123182334,5-Dichloro-2-n-octyl-3-isothiazolidinone 1-oxide

Produkt 1

HCID 213935562-Octyl-4,5-dichloro-3-isothiazolidinone 1,1-dioxide

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6212ChloroformLösungsmittel2×

Reaktionsbedingungen

Temperatur
50 °C

Versuchsvorschrift

To a solution of 2.84g. (0.01 mole) of 2-octyl-4,5-dichloro-3-isothiazolidinone 1-oxide in 20 ml. of chloroform at 0° C. is added a solution of 5.4g. (0.025 mole) of 81% pure m-chloroperbenzoic acid in 100 ml. of chloroform. The mixture is stirred for three days at 50° C. The reaction mixture is filtered and the filtrate is washed with a dilute sodium bicarbonate solution. The chloroform layer is dried over magnesium sulfate and evaporated to give the crude product.

Aufarbeitung

  1. filtrationThe reaction mixture is filtered
  2. washthe filtrate is washed with a dilute sodium bicarbonate solution
  3. dry with materialThe chloroform layer is dried over magnesium sulfate
  4. customevaporated

Quellen und Nachweise

ORD-Eintrag
ord-4b7f6d6f84de46dcb86be3ec4706329e
Quelldatensatz
uspto-grants-1977_12
Patentnummer
US04062859

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