4-Cyclohexylbenzene-1-thiol → 6-[4-(4-Cyclohexyl-phenylmercapto)-butoxy]-4,4-di-n-hexyl-4H-3,1-benzoxazin-2-one
Reaktionsgleichung
Cl[CH2:2][CH2:3][CH2:4][CH2:5][O:6][C:7]1[CH:8]=[CH:9][C:10]2[NH:15][C:14](=[O:16])[O:13][C:12]([CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:11]=2[CH:29]=1.[CH:30]1([C:36]2[CH:41]=[CH:40][C:39]([SH:42])=[CH:38][CH:37]=2)[CH2:35][CH2:34][CH2:33][CH2:32][CH2:31]1>>[CH:30]1([C:36]2[CH:37]=[CH:38][C:39]([S:42][CH2:2][CH2:3][CH2:4][CH2:5][O:6][C:7]3[CH:8]=[CH:9][C:10]4[NH:15][C:14](=[O:16])[O:13][C:12]([CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:11]=4[CH:29]=3)=[CH:40][CH:41]=2)[CH2:31][CH2:32][CH2:33][CH2:34][CH2:35]1Komponenten
3
Versuchsvorschrift
Prepared analogously to Example 1 from 6-(4-chlorobutoxy)-4,4-di-n-hexyl-4H-3,1-benzoxazin-2-one [oil, RF value: 0.7; silica gel plate; chloroform/acetone (19:1)] and 4-cyclohexyl-thiophenol.
Quellen und Nachweise
- ORD-Eintrag
- ord-b578cffd84f74e8a810405b2f1018631
- Quelldatensatz
- uspto-grants-1985_05