Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Sodium Hydroxide | HCID 14798 | — |
| Edukt | Hydrazine hydrate (1:1) | HCID 24654 | — |
| Edukt | Diazene, 1,2-bis(2-chlorophenyl)-, 1-oxide | HCID 83576 | — |
| Katalysator | Nickel | HCID 935 | — |
| Lösungsmittel | Methanol | HCID 887 | — |
| Lösungsmittel | Water | HCID 962 | — |
| Produkt | 3,3'-Dichlorobenzidine | HCID 7070 | — |
| Produkt | Nitrous Acid | HCID 24529 | — |
Reaktionsschritte
53.4 g of 2,2'-dichloroazoxybenzene are stirred in 60 ml of methanol. 0.6 g of sodium hydroxide and 11.8 ml of hydrazine hydrate are added and the mixture is warmed to 65° C. After Raney nickel has been added (a total of about 0.05 g in 2-3 portions) vigorous evolution of nitrogen starts. The reduction has ended after 30 minutes. The mixture is cooled to 10° C. and diluted with water and the 2,2'-dichlorohydrazobenzene which has crystallised out is filtered off and washed with water until neutral. After the rearrangement to 3,3'-dichlorobenzidine and tetrazotisation with nitrous acid, a yield of 86% of theory is obtained.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US04550207 |
|---|
| Quelldatensatz | uspto-grants-1985_10 |
|---|
| ORD ID | ord-a4b05ef6fb064d9e9cdad462c02b34a0 |
|---|
| Quellennotiz | uspto-grants-1985_10 |
|---|
