Leucine, N-carboxy-, N-benzyl ester, L- → Z-Leu-phe-OH
Reaktionsgleichung
[CH2:1]([O:8][C:9]([NH:11][C@H:12]([C:17]([NH:19][C@H:20]([C:25]([OH:27])=[O:26])[CH2:21][CH:22]([CH3:24])[CH3:23])=[O:18])[CH2:13][CH:14]([CH3:16])[CH3:15])=[O:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:28](OC(N[C@H](C(O)=O)CC(C)C)=O)[C:29]1C=CC=C[CH:30]=1.Cl.COC(=O)[C@H](CC(C)C)N>>[CH2:1]([O:8][C:9]([NH:11][C@H:12]([C:17]([NH:19][C@H:20]([C:25]([OH:27])=[O:26])[CH2:21][C:22]1[CH:23]=[CH:30][CH:29]=[CH:28][CH:24]=1)=[O:18])[CH2:13][CH:14]([CH3:16])[CH3:15])=[O:10])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1Komponenten
4
Versuchsvorschrift
N-Benzyloxycarbonyl-L-leucyl-L-leucine (m.p. 70°-76° C.) from N-benzyloxycarbonyl-L-leucine and L-leucine methyl ester hydrochloride.
Quellen und Nachweise
- ORD-Eintrag
- ord-3f37edfa64494ec0834f90b2e4cba69b