1,6-Diiodohexane → 1,1'-Hexane-1,6-diylbis{5,5-dimethyl-3-[4-nitro-3-(trifluoromethyl)phenyl]imidazolidine-2,4-dione}

HRID 468570

Reaktionsgleichung

Reaktionsgleichung von HRID 468570
[CH2:1](N1C(C)(C)C(=O)N(C2C=CC([N+]([O-])=O)=C(C(F)(F)F)C=2)C1=O)[CH2:2][CH2:3][CH2:4][N:5]1[C:9]([CH3:11])([CH3:10])[C:8](=[O:12])[N:7]([C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-:21])=[O:20])=[C:15]([C:22]([F:25])([F:24])[F:23])[CH:14]=2)[C:6]1=[O:26].I[CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55]I>>[CH2:4]([N:5]1[C:9]([CH3:11])([CH3:10])[C:8](=[O:12])[N:7]([C:50]2[CH:55]=[CH:54][C:53]([N+:19]([O-:21])=[O:20])=[C:52]([C:22]([F:23])([F:25])[F:24])[CH:51]=2)[C:6]1=[O:26])[CH2:3][CH2:1][CH2:2][CH2:3][CH2:4][N:5]1[C:9]([CH3:11])([CH3:10])[C:8](=[O:12])[N:7]([C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-:21])=[O:20])=[C:15]([C:22]([F:24])([F:23])[F:25])[CH:14]=2)[C:6]1=[O:26]

Komponenten

3

Edukt 2

HCID 123731,6-DiiodohexaneHCID 497638371,1'-Butane-1,4-diylbis{5,5-dimethyl-3-[4-nitro-3-(trifluoromethyl)phenyl]imidazolidine-2,4-dione}

Produkt 1

HCID 497638381,1'-Hexane-1,6-diylbis{5,5-dimethyl-3-[4-nitro-3-(trifluoromethyl)phenyl]imidazolidine-2,4-dione}Ausbeute 27 %

Versuchsvorschrift

The experimental protocol used is the same as that described for the synthesis of the compound of Example 1, 1,6-diiodohexane replacing 1,4-dibromobutane. The expected compound is obtained in the form of a light yellow solid with a yield of 27%. Melting point: 187-188° C.

Quellen und Nachweise

ORD-Eintrag
ord-3ea8d0c5a6b24f7daeb679b1c6c2cb68
Quelldatensatz
uspto-grants-2014_01
Patentnummer
US08624037B2

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