Nitric Acid → HCID 178512576, Verbindung

HRID 47204

Reaktionsgleichung

Reaktionsgleichung von HRID 47204
[NH2:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[C:4]([N+]([O-])=O)[CH:3]=1.[N+:12]([O-:15])([OH:14])=[O:13].[N:16]#[C:17][NH2:18]>CCO>[N+:12]([O-:15])([OH:14])=[O:13].[OH:8][C:5]1[CH:6]=[CH:7][C:2]([NH:1][C:17]([NH2:18])=[NH:16])=[C:3]([N+:12]([O-:15])=[O:13])[CH:4]=1

Komponenten

5

Edukt 3

HCID 944Nitric AcidHCID 9864CyanamideHCID 34174194-Amino-2-Nitrophenol

Produkt 1

HCID 178512576HCID 178512576, VerbindungAusbeute 54 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

A mixture of 4-amino-2-nitrophenol (25 mmol, 3.85 g) in EtOH (6 mL) on an ice bath was treated with nitric acid (69% aq soln.; 1.8 mL). To this of cyanamide (50% aq. soln.; 4 mL) was added. The reaction mixture was refluxed under N2 for 22 h. The solvent was evaporated. The dark brown solid residue was washed with EtOH and was dried under high vacuum to afford the title compound as a grey solid (3.53 g, 54%).

Aufarbeitung

  1. temperatureThe reaction mixture was refluxed under N2 for 22 h
  2. customThe solvent was evaporated
  3. washThe dark brown solid residue was washed with EtOH
  4. customwas dried under high vacuum

Quellen und Nachweise

ORD-Eintrag
ord-1668630a45044138b5579a1df16f23ff
Quelldatensatz
uspto-grants-2004_03
Patentnummer
US06699854B2

Verknüpfte Notizen

Wird geladen…