HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Ethyl Thioglycolate → Ethyl (3-phenoxybenzylthio)acetate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Ethyl Thioglycolate | HCID 12185 | — |
| Edukt | 1-(Chloromethyl)-4-phenoxybenzene | HCID 520994 | — |
| Edukt | Sodium ethoxide | HCID 2723922 | — |
| Edukt | Ethyl (4-methylbenzylthio)acetate | HCID 4107274 | — |
| Lösungsmittel | Ethanol | HCID 702 | — |
| Produkt | Ethyl (3-phenoxybenzylthio)acetate | HCID 53984256 | — |
Reaktionsschritte
The procedure is as in Example 29 for the preparation of ethyl (4-methylbenzylthio)acetate, starting with 1-chloromethyl-4-phenoxybenzene (21.5 g), a 2M ethanolic solution of sodium ethylate (50 cc) and ethyl 2-mercaptoacetate (12.2 g) in ethanol (200 cc). Ethyl (3-phenoxybenzylthio)acetate (28.8 g) is thereby obtained, and is used in the crude state in the subsequent syntheses.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04886835 |
| Quelldatensatz | uspto-grants-1989_12 |
| ORD ID | ord-133d19a2715a462a97cf308f0d226e38 |
| Quellennotiz | uspto-grants-1989_12 |