HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Batyl Alcohol → 1-O-Octadecyl-3-O-[2-[2-(2-trityloxyethoxy)ethoxy]ethyl]glycerol
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Batyl Alcohol | HCID 3681 | — |
| Edukt | Trityl chloride | HCID 6456 | — |
| Edukt | Triethylene Glycol | HCID 8172 | — |
| Edukt | Sodium hydride | HCID 24758 | — |
| Edukt | Sodium 4-methylbenzenesulfonate | HCID 3720192 | — |
| Lösungsmittel | Pyridine | HCID 1049 | — |
| Produkt | 1-O-Octadecyl-3-O-[2-[2-(2-trityloxyethoxy)ethoxy]ethyl]glycerol | HCID 14877714 | 42,2% |
Reaktionsschritte
10.3 g (30 millimole) of batyl alcohol, 6.1 g (32 millimole) of sodium p-toluenesulfonate, 50 ml of pyridine, 1.6 g (40 millimole) of 60% oily sodium hydride, 45 g (300 millimole) of triethylene glycol, and 8.4 g (30 millimole) of trityl chloride were treated by following a procedure similar to that of Working Example 1, to give 9.1 g (42%) of the above-captioned compound.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04889953 |
| Quelldatensatz | uspto-grants-1989_12 |
| ORD ID | ord-86ee1e5ae9874216bdc3b8f1993af70d |
| Quellennotiz | uspto-grants-1989_12 |