Hydroquinone → N-dodecyl-2-pyrrolidone pentachlorophenol

HRID 487239

Reaktionsgleichung

[CH2:1]([N:13]1[CH2:17][CH2:16][CH2:15][C:14]1=[O:18])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Cl:19][C:20]1[C:25]([OH:26])=[C:24]([Cl:27])[C:23]([Cl:28])=[C:22]([Cl:29])[C:21]=1[Cl:30].C1(C=CC(O)=CC=1)O>>[CH2:1]([N:13]1[CH2:17][CH2:16][CH2:15][C:14]1=[O:18])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Cl:19][C:20]1[C:25]([OH:26])=[C:24]([Cl:27])[C:23]([Cl:28])=[C:22]([Cl:29])[C:21]=1[Cl:30]

Komponenten

Edukt 3

HCID 785Hydroquinone

HCID 992Pentachlorophenol

HCID 624591-Lauryl-2-pyrrolidone

Produkt 1

HCID 86745508N-dodecyl-2-pyrrolidone pentachlorophenol

Reaktionsbedingungen

Temperatur: 120 °C

Versuchsvorschrift

Example XXVIII is repeated except that only 12.17 g (0.05 mole) of N-dodecyl-2-pyrrolidone is used and 13.32 g (0.05 mole) of pentachlorophenol is substituted for 11.1 g of hydroquinone and the resulting melt is heated at 120° C. for 30 minutes. A solid crystalline micellular complex of 1:1 molar N-dodecyl-2-pyrrolidone/pentachlorophenol is formed.

Quellen und Nachweise

ORD-Eintrag: ord-1e777dc81ed044a2b68b7145771be14a
Quelldatensatz: uspto-grants-1994_03
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US05294644

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