Methyl 2-[(2-methoxy-2-oxoethyl)amino]acetate → N-(2-methoxy-2-oxoethyl)-N-[3-(tetradecyloxy)benzoyl]glycine methyl ester

HRID 488247Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 488247
[CH2:1]([O:15][C:16]1[CH:17]=[C:18]([CH:22]=[CH:23][CH:24]=1)[C:19]([OH:21])=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[NH:25]([CH2:31][C:32]([O:34][CH3:35])=[O:33])[CH2:26][C:27]([O:29][CH3:30])=[O:28]>>[CH3:35][O:34][C:32](=[O:33])[CH2:31][N:25]([CH2:26][C:27]([O:29][CH3:30])=[O:28])[C:19](=[O:21])[C:18]1[CH:22]=[CH:23][CH:24]=[C:16]([O:15][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])[CH:17]=1

Komponenten

3

Edukt 2

HCID 428827Methyl 2-[(2-methoxy-2-oxoethyl)amino]acetateHCID 32623113-(Tetradecyloxy)benzoic acid

Produkt 1

HCID 19091823N-(2-methoxy-2-oxoethyl)-N-[3-(tetradecyloxy)benzoyl]glycine methyl ester

Versuchsvorschrift

The conversion of 3-(tetradecyloxy)benzoic acid to the acid chloride followed by treatment with dimethyl iminodiacetate as in Example 1 gave N-(2-methoxy-2-oxoethyl)-N-[3-(tetradecyloxy)benzoyl]glycine methyl ester, mp <23°. The nmr and mass spectra were consistent with the structure.

Quellen und Nachweise

ORD-Eintrag
ord-3d931b572aa443c49df484eedc17664f
Quelldatensatz
uspto-grants-1994_03
Patentnummer
US05298652

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