Azobisisobutyronitrile → Methyl 3-(bromomethyl)benzoate

HRID 4912

Reaktionsgleichung

Reaktionsgleichung von HRID 4912
[C:1]1([CH3:11])[CH:6]=[CH:5][CH:4]=[C:3]([C:7]([O:9][CH3:10])=[O:8])[CH:2]=1.C1C(=O)N([Br:19])C(=O)C1.CC(N=NC(C#N)(C)C)(C#N)C>>[Br:19][CH2:11][C:1]1[CH:2]=[C:3]([CH:4]=[CH:5][CH:6]=1)[C:7]([O:9][CH3:10])=[O:8]

Komponenten

4

Edukt 3

HCID 6547AzobisisobutyronitrileHCID 7435Benzoic acid, 3-methyl-, methyl esterHCID 67184N-bromobutanimide

Produkt 1

HCID 517981Methyl 3-(bromomethyl)benzoate

Versuchsvorschrift

Methyl m-toluate was brominated with NBS and AIBN as described in Example 21 to give methyl m-bromomethylbenzoate, and this was further reacted with triethyl phosphite as described in Example 2 without further purification.

Quellen und Nachweise

ORD-Eintrag
ord-72cd4b260c0043e8aa2503a92dce1f5e
Quelldatensatz
uspto-grants-1993_09
Patentnummer
US05242908

Verknüpfte Notizen

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