m-Chloroperbenzoic acid → HCID 59750363, Verbindung

HRID 499528Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 499528
[CH3:1][S:2][C:3]1[N:8]=[CH:7][C:6]([C:9]2[S:10][C:11]3[CH:19]=[CH:18][CH:17]=[CH:16][C:12]=3[C:13](=[O:15])[N:14]=2)=[CH:5][CH:4]=1.ClC1C=CC=C(C(OO)=[O:28])C=1>C(Cl)(Cl)Cl>[CH3:1][S:2]([C:3]1[N:8]=[CH:7][C:6]([C:9]2[S:10][C:11]3[CH:19]=[CH:18][CH:17]=[CH:16][C:12]=3[C:13](=[O:15])[N:14]=2)=[CH:5][CH:4]=1)=[O:28]

Komponenten

4

Edukt 2

HCID 70297m-Chloroperbenzoic acidHCID 59750109HCID 59750109, Verbindung

Produkt 1

HCID 59750363HCID 59750363, VerbindungAusbeute 28,1 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6212ChloroformLösungsmittel2×

Versuchsvorschrift

2-[6-(Methylthio)-3-pyridyl]-4H-1,3-benzothiazine-4-one (0.28 g, 1.00 mmol) was dissolved in chloroform (30 ml), and a solution of 3-chloroperbenzoic acid (ca. 77%, 0.23 g, 1.00 mmol) in chloroform (10 ml) was added dropwise thereto. The mixture was stirred at room temperature for 1 hr. The solvent was evaporated, and the residue was recrystallized from ethanol to give the titled compound (0.085 g, 28%) as pale yellow crystals.

Aufarbeitung

  1. customThe solvent was evaporated
  2. customthe residue was recrystallized from ethanol

Quellen und Nachweise

ORD-Eintrag
ord-663fbab0b7dc448488f7e7686874b009
Quelldatensatz
uspto-grants-2010_08
Patentnummer
US07767665B2

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