S([O-])([O-])(=O)=[O:2].[Ni+2:6].S([O-])([O-])(=O)=[O:8].[Mn+2:12].S([O-])([O-])(=O)=[O:14].[Co+2:18].S([O-])([O-])(=O)=[O:20].[NH4+].[NH4+].[OH-:26].[Na+]>>[OH-:2].[Co+2:18].[Mn+2:12].[Ni+2:6].[OH-:8].[OH-:14].[OH-:20].[OH-:26].[OH-:2]In a 2-L (liter) reaction vessel, 1.8 L of the mother liquor obtained in the above-described Example 1 was poured, and agitated at 250 rpm while maintaining the internal temperature at 50±1° C. To this, while supplying an aqueous solution of metal sulfates containing 1.5 mol/L of nickel sulfate, 1.5 mol/L of manganese sulfate and 1.5 mol/L of cobalt sulfate at a flow rate of 0.4 L/hr; and simultaneously supplying a 1.5 mol/L aqueous solution of ammonium sulfate at a flow rate of 0.03 L/hr; an 18 mol/L aqueous solution of sodium hydroxide was continuously supplied so that the pH in the reaction vessel was maintained at 11.05±0.05. The mother liquor in the reaction vessel was periodically extracted, and the slurry was concentrated until the final slurry concentration became about 1000 g/L. The nickel concentration in the periodically extracted mother liquor from the reaction vessel was 22 ppm. After the target slurry concentration had been obtained, the slurry was aged at 50° C. for 5 hours, filtration and water washing were repeated to obtain coagulated particles of a co-precipitated nickel-manganese-cobalt hydroxide.
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