Nitric Acid → 2,9-Dimethyl-5-nitro-1,10-phenanthroline

HRID 516426

Reaktionsgleichung

Reaktionsgleichung von HRID 516426
[CH3:1][C:2]1[CH:15]=[CH:14][C:13]2[C:4](=[C:5]3[C:10](=[CH:11][CH:12]=2)[CH:9]=[CH:8][C:7]([CH3:16])=[N:6]3)[N:3]=1.[N+:17]([O-])([OH:19])=[O:18].S(=O)(=O)(O)O>>[N+:17]([C:11]1[CH:12]=[C:13]2[C:4]([N:3]=[C:2]([CH3:1])[CH:15]=[CH:14]2)=[C:5]2[C:10]=1[CH:9]=[CH:8][C:7]([CH3:16])=[N:6]2)([O-:19])=[O:18]

Komponenten

4

Edukt 3

HCID 944Nitric AcidHCID 1118Sulfuric AcidHCID 652372,9-Dimethyl-1,10-phenanthroline

Produkt 1

HCID 3797642,9-Dimethyl-5-nitro-1,10-phenanthroline

Versuchsvorschrift

Specifically, 2,9-dimethyl-1,10-phenanthroline shown by the formula (A) in FIG. 1 is reacted with an acid mixture composed of nitric acid and sulfuric acid to give 5-nitro-2,9-dimethyl-1,10-phenanthroline shown by the formula (B) in FIG. 1. The 5-nitro-2,9-dimethyl-1,10-phenanthroline is then reacted with selenium dioxide to give a dialdehyde compound shown by the formula (C) in FIG. 1. This dialdehyde compound is then oxidized to obtain the compound of the formula (1).

Aufarbeitung

  1. customis reacted with an acid mixture

Quellen und Nachweise

ORD-Eintrag
ord-0f59cd525fb64804ac07fb173d4489ac
Quelldatensatz
uspto-grants-2015_08
Patentnummer
US09110047B2

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